Copper Acetate Monohydrate

Chemical Name: Copper(II) acetate monohydrate / Cupric acetate monohydrate
CAS Number: 6046-93-1 (monohydrate), 142-71-2 (anhydrous)
EINECS Number: 205-553-3
Molecular Formula: Cu(CH₃COO)₂·H₂O or C₄H₆CuO₄·H₂O
Molecular Weight: 199.65 g/mol (monohydrate), 181.63 g/mol (anhydrous)
Properties & Applications & PackagesInquiry
Technical Datas:

Items

Standards

Content(Cu(CH3COO)2·H2O)

≥98%

Insoluble Substances

≤0.05%

Sulfates (SO4)

≤0.02%

Nitrates

-

Chlorides (Cl)

≤50mg/kg

Iron (Fe)

≤50mg/kg

Lead (Pb)

≤5mg/kg

Non-sludging to Hydrogen Sulfide

≤0.3%



Physical Properties
-Appearance: Dark green crystalline solid or blue-green powder
-Odor: Odorless
-Crystal Structure: Monoclinic, adopts a "paddle wheel" dimeric structure with one water molecule per copper atom
-Density: 1.882 g/cm³ (monohydrate)
-Solubility in Water:
Cold water: 7.2 g/100 mL
Hot water: 20 g/100 mL
-Solubility: Soluble in alcohol; slightly soluble in ether and glycerol
-Melting Point: Undetermined for monohydrate; anhydrous form melts at 115°C with decomposition
-Boiling Point: 240°C (464°F; 513 K)
-Refractive Index: 1.545 (monohydrate)
Chemical Properties
-Thermal Decomposition: Decomposes upon heating; the anhydrous form decomposes at 115°C
-Structure Feature: Contains dinuclear copper centers with Cu-Cu distance of 2.62 Å (0.262 nm), showing antiferromagnetic coupling at low temperatures (<90 K)
-Reactivity: Acts as an oxidizing agent in organic synthesis; reacts with strong acids to produce acetic acid
Main Applications and Uses
1. Chemical Synthesis
Oxidizing Agent: Used in organic synthesis, particularly in the Eglinton reaction for coupling terminal alkynes to form 1,3-diynes
Catalyst: Employed in hydroamination reactions and as a precursor for other copper catalysts
Reagent: Used in the synthesis of ynamines and other specialized organic compounds
2. Analytical Chemistry
Barfoed's Test: Serves as an oxidizing agent to test for the presence of monosaccharides
Copper Soap Assay: Used as a precursor to copper-fatty acid complexes for colorimetric determination of free fatty acids
Fehling's Reagent: Used in the preparation of Fehling's solution for testing reducing sugars
3. Agricultural Applications
Fungicide: Used as a fungicide and pesticide; reacts with arsenic trioxide to form copper acetoarsenite (Paris Green), a powerful insecticide and fungicide
4. Industrial Applications
Ceramic Pigment: Used as a colorant in ceramics, producing green and blue-green hues
Textile Dyeing: Applied in textile dyeing processes
Metal Finishing: Used in chemical coloring of copper to produce bronze patinas 


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